Methanol → HCID 178496795, Verbindung

Reaktionsgleichung

CO[C:3](OC)=[N:4][NH:5][C:6]([O:8][CH3:9])=[O:7].[CH3:12][NH2:13].[CH3:14][OH:15]>>[CH3:14][O:15][CH2:12][NH:13][CH:3]=[N:4][NH:5][C:6]([O:8][CH3:9])=[O:7]

Komponenten

Edukt 3

HCID 887Methanol

HCID 6329Methylamine

HCID 10986557HCID 10986557, Verbindung

Produkt 1

HCID 178496795HCID 178496795, VerbindungAusbeute 76 %

Versuchsvorschrift

0.95 g (5.00 mmol) of methyl N′-dimethoxymethylenehydrazinecarboxylate (85% pure) was admixed with 3.57 g of a 44% strength solution of methylamine (50 mmol) in methanol, and the mixture was stirred at room temperature for 3 days. Work-up and removal of the solvent gave 0.85 g (76%) of methyl N′-(methoxymethylaminomethylene)hydrazinecarboxylate in the form of an oil.