HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
Hydrochloric Acid → Cyclopentene
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | Hydrochloric Acid | HCID 313 | — |
| Edukt | tert-BUTYL CHLORIDE | HCID 10486 | — |
| Edukt | Chlorocyclopentane | HCID 70252 | — |
| Edukt | Trichlorocyclopentylsilane | HCID 84533 | — |
| Edukt | Cyclopentyldichlorosilane | HCID 71344807 | — |
| Produkt | Cyclopentene | HCID 8882 | 58,4% |
| Produkt | Trichlorosilane | HCID 24811 | — |
Reaktionsschritte
The reaction was carried out under the same condition as in Example 3, except that the same amount of t-butyl chloride was used as the hydrogen chloride source. A mixture of cyclopentyl chloride and t-butyl chloride having the mixing ratio of 1:2 was reacted with metallic silicon at 280° C. to give 30.1 g of reaction products. The reaction products contained 6.2 g (39.1%) of cyclopentyldichlorosilane and 0.3 g (1.6%) of cyclopentyltrichlorosilane. There were not starting materials unreacted. As other by-products, 3.7 g (58.4%) of cyclopentene, 2.9 g of trichlorosilane and unconfirmed materials were obtained.
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US06911552B2 |
| Quelldatensatz | uspto-grants-2005_06 |
| ORD ID | ord-9b6b831658204195936c22d1f14da4cc |
| Quellennotiz | uspto-grants-2005_06 |