Tributylstannane → 1-(tributylstannyl)-1E-undecen-3-ol

HRID 1073646Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1073646
[CH:1]#[C:2][CH:3]([OH:12])[CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11].[CH2:13]([SnH:17]([CH2:22][CH2:23][CH2:24][CH3:25])[CH2:18][CH2:19][CH2:20][CH3:21])[CH2:14][CH2:15][CH3:16]>>[CH2:22]([Sn:17]([CH2:13][CH2:14][CH2:15][CH3:16])([CH2:18][CH2:19][CH2:20][CH3:21])/[CH:1]=[CH:2]/[CH:3]([OH:12])[CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11])[CH2:23][CH2:24][CH3:25]

Komponenten

3

Edukt 2

HCID 5948TributylstannaneHCID 2477661-Undecyn-3-ol

Produkt 1

HCID 121582911-(tributylstannyl)-1E-undecen-3-ol

Reaktionsbedingungen

Temperatur
120 °C

Versuchsvorschrift

To 0.07 g (0.42 mmol) of the titled product of Example 7 is added 0.15 g (0.5 mmol) of tri-n-butyltin hydride and 20 mg of azoisobutyronitrile (AIBN). The reaction mixture was heated to 120° C. for 2 hours. Afterwards, it was cooled to room temperature and pumped at high vacuum overnight. The crude reaction mixture was then heated to 90° C. and maintained at high vacuum for 2 additional hours. Upon cooling to room temperature, the crude product was used as is.

Aufarbeitung

  1. temperatureAfterwards, it was cooled to room temperature
  2. custompumped at high vacuum overnight
  3. customThe crude reaction mixture
  4. temperaturewas then heated to 90° C.
  5. temperaturemaintained at high vacuum for 2 additional hours
  6. temperatureUpon cooling to room temperature

Quellen und Nachweise

ORD-Eintrag
ord-1c275844a8354614ab54f2b7bfa78c94
Quelldatensatz
uspto-grants-1990_11
Patentnummer
US04970234

Notizen zur Reaktion

Wird geladen…