Methylhydroquinone → Methyl-1,4-benzoquinone

HRID 1074900

Reaktionsgleichung

Reaktionsgleichung von HRID 1074900
[CH3:1][C:2]1[CH:8]=[C:7]([OH:9])[CH:6]=[CH:5][C:3]=1[OH:4].Cl[O-]>C(Cl)(Cl)Cl>[CH3:1][C:2]1[C:3](=[O:4])[CH:5]=[CH:6][C:7](=[O:9])[CH:8]=1

Komponenten

4

Edukt 2

HCID 7253MethylhydroquinoneHCID 61739Hypochlorite

Produkt 1

HCID 11122Methyl-1,4-benzoquinone

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 6212ChloroformLösungsmittel

Versuchsvorschrift

2-methyl hydroquinone (1b) of 3.0 g (24 mmol) is dissolved in 150 ml of chloroform, wherein 100 ml each of hypochloride solution which have been so prepared as mentioned above are added and each reaction is made in the same way as described in Example 1, and then 2-methyl benzoquinone (IIb) is obtained. Table below shows the yields of isolation corresponding to each case of the investigation:

Aufarbeitung

  1. additionabove are added

Quellen und Nachweise

ORD-Eintrag
ord-054885253cbc4b59beba4cc150ab1079
Quelldatensatz
uspto-grants-1983_07
Patentnummer
US04394315

Verknüpfte Notizen

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