N-bromobutanimide → 5-Bromo-2,2-diphenyl-1,3-benzodioxol

HRID 1087448

Reaktionsgleichung

Reaktionsgleichung von HRID 1087448
[Br:1]N1C(=O)CCC1=O.[C:9]1([C:15]2([C:24]3[CH:29]=[CH:28][CH:27]=[CH:26][CH:25]=3)[O:19][C:18]3[CH:20]=[CH:21][CH:22]=[CH:23][C:17]=3[O:16]2)[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=1>C(Cl)(Cl)Cl>[Br:1][C:22]1[CH:21]=[CH:20][C:18]2[O:19][C:15]([C:9]3[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=3)([C:24]3[CH:25]=[CH:26][CH:27]=[CH:28][CH:29]=3)[O:16][C:17]=2[CH:23]=1

Komponenten

4

Edukt 2

HCID 67184N-bromobutanimideHCID 3439592,2-Diphenyl-1,3-benzodioxole

Produkt 1

HCID 223195155-Bromo-2,2-diphenyl-1,3-benzodioxol

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 6212ChloroformLösungsmittel

Versuchsvorschrift

18.75 g of N-bromosuccinimide are added to a solution of 27.4 g of 2,2-diphenyl-1,3-benzodioxol in 80 ml of chloroform and the mixture was boiled at reflux for 20 hours. The reaction mixture was cooled and the separated succinimide was filtered off. The filtrate was washed with water, dried over sodium sulphate and the solvent was removed in a vacuum. By crystallization of the residue from ethanol, there was obtained 5-bromo-2,2-diphenyl-1,3-benzodioxol as white crystals of melting point 88-89° C.

Aufarbeitung

  1. temperatureat reflux for 20 hours
  2. temperatureThe reaction mixture was cooled
  3. filtrationthe separated succinimide was filtered off
  4. washThe filtrate was washed with water
  5. dry with materialdried over sodium sulphate
  6. customthe solvent was removed in a vacuum
  7. customBy crystallization of the residue from ethanol

Quellen und Nachweise

ORD-Eintrag
ord-9286a44c767a4eeca6c2c255773bac93
Quelldatensatz
uspto-grants-1991_07
Patentnummer
US05036064

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