Azobisisobutyronitrile → HCID 22162023, Verbindung

HRID 1088904

Reaktionsgleichung

Reaktionsgleichung von HRID 1088904
[CH2:1]([SH:6])[CH2:2][CH2:3][CH2:4][SH:5].[CH2:7]=[CH:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH3:24].N([C:32]([CH3:36])([CH3:35])C#N)=NC(C)(C)C#N>>[CH2:7]([S:5][CH2:4][CH2:3][CH2:2][CH2:1][S:6][CH2:21][CH2:20][CH2:19][CH2:18][CH2:17][CH2:16][CH2:15][CH2:14][CH2:13][CH2:12][CH2:11][CH2:10][CH2:9][CH2:8][CH2:7][CH2:36][CH2:32][CH3:35])[CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH3:24]

Komponenten

4

Edukt 3

HCID 6547AzobisisobutyronitrileHCID 82171-OctadeceneHCID 791481,4-Butanedithiol

Produkt 1

HCID 22162023HCID 22162023, Verbindung

Versuchsvorschrift

The procedure used was essentially the same as described in Example 1. A stirred mixture of 12.22 g. (0.1 moles) of 1,4-butane dithiol and 50.5 g. (0.2 moles) of 1-octadecene were reacted at 80° C. in the presence of 0.5 g. of 2,2'-azobis(isobutyronitrile). The reaction mixture was recrystallized twice from hexanes (2×300 g.) collected by filtration, washed with 100 g. of cold hexanes, and air dried to yield 45.5 g. of pure product. Anal. Calcd. for C40H82S2 : C, 76.6; H, 13.2; S, 10.2 Found: C, 76.2; H, 12.9: S, 10.2.

Aufarbeitung

  1. additionA stirred mixture of 12.22 g
  2. customThe reaction mixture was recrystallized twice from hexanes (2×300 g.)
  3. filtrationcollected by filtration
  4. washwashed with 100 g
  5. dry with materialof cold hexanes, and air dried
  6. customto yield 45.5 g

Quellen und Nachweise

ORD-Eintrag
ord-5bd62c5c015c4908bd8b53dd9804abc2
Quelldatensatz
uspto-grants-1990_10
Patentnummer
US04963607

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