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HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
HRID 1089037Erstellt: 26. Oktober 2026

Resorcinol → 1,3-Benzenediol, o-octanoyl-

https://huagongshe.com/reaction/1089037

Reaktionsgleichung

Beteiligte Stoffe

RolleNameHCIDEinwaage
EduktResorcinolHCID 5054—
EduktOctanoic anhydrideHCID 69340—
EduktHydroquinone mono-acetateHCID 21327627—
EduktOctanoyloxy-3-hydroxy benzene (resorcinol monooctanoate)HCID 131716678—
Katalysator4-(Dimethylamino)pyridineHCID 14284—
LösungsmittelTriethylamineHCID 8471—
LösungsmittelEthyl AcetateHCID 8857—
Produkt1,3-Benzenediol, o-octanoyl-HCID 14549096—

Reaktionsschritte

Adapting the method of synthesis disclosed in D. Johnston, "Preparation of Hydroquinone Monoacetate," Chemistry & Industry 24:1000 (1982) (which is incorporated herein by reference), it is expected that resorcinol may be combined with about an equimolar amount of dioctanoic acid anhydride, and ethyl acetate solvent, a non-nucleophilic solvent, in the presence of 4-dimethylaminopyridine, a catalyst, and a base, such as triethylamine, at room temperature, to produce the desired 1 octanoyloxy-3-hydroxy benzene (resorcinol monooctanoate).

Herkunft & Nachweise

DOI10.6084/m9.figshare.5104873.v1
PatentnummerUS04964870
Quelldatensatzuspto-grants-1990_10
ORD IDord-6ce8d7de2557459fa3c9e28bf34037b6
Quellennotizuspto-grants-1990_10