1,1-Dichlorosilacyclobutane → 1,1-Diacetoxysilacyclobutane

HRID 1089317

Reaktionsgleichung

Reaktionsgleichung von HRID 1089317
C[Si]([CH2:5][C:6]([O-:8])=[O:7])(C)C.Cl[Si:10]1(Cl)[CH2:13][CH2:12][CH2:11]1>>[C:6]([O:8][Si:10]1([O:8][C:6](=[O:7])[CH3:5])[CH2:13][CH2:12][CH2:11]1)(=[O:7])[CH3:5]

Komponenten

3

Edukt 2

HCID 753731,1-DichlorosilacyclobutaneHCID 225582202-Trimethylsilylacetate

Produkt 1

HCID 150659191,1-Diacetoxysilacyclobutane

Reaktionsbedingungen

Temperatur
25 °C

Versuchsvorschrift

To 30.0 g trimethylsilylacetate was added 16.0 g 1,1-dichlorosilacyclobutane. The reactants were stirred for one hour at 25 ° C. and fractional distillation performed on the reaction mixture. The title compound was isolated as a clear, colorless fluid. The yield was 14.6 g (81.4%). The structure of the product was confirmed by mass spectroscopy and nuclear magnetic resonance spectroscopy (NMR).

Aufarbeitung

  1. distillationfractional distillation

Quellen und Nachweise

ORD-Eintrag
ord-f4d327f92e4a4de5b56a0b7b9b71e94e
Quelldatensatz
uspto-grants-1990_10
Patentnummer
US04965367

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