Ethanolamine → Ethanol, 2,2',2''-[(2,4,6-trinitro-1,3,5-benzenetriyl)triimino]tris-

HRID 1090339

Reaktionsgleichung

Reaktionsgleichung von HRID 1090339
[N+:1]([C:4]1[C:9](Cl)=[C:8]([N+:11]([O-:13])=[O:12])[C:7](Cl)=[C:6]([N+:15]([O-:17])=[O:16])[C:5]=1Cl)([O-:3])=[O:2].[CH2:19]([CH2:21][NH2:22])[OH:20]>CO>[N+:1]([C:4]1[C:9]([NH:22][CH2:21][CH2:19][OH:20])=[C:8]([N+:11]([O-:13])=[O:12])[C:7]([NH:22][CH2:21][CH2:19][OH:20])=[C:6]([N+:15]([O-:17])=[O:16])[C:5]=1[NH:22][CH2:21][CH2:19][OH:20])([O-:3])=[O:2]

Komponenten

4

Edukt 2

HCID 700EthanolamineHCID 175181,3,5-Trichloro-2,4,6-trinitrobenzene

Produkt 1

HCID 3089546Ethanol, 2,2',2''-[(2,4,6-trinitro-1,3,5-benzenetriyl)triimino]tris-Ausbeute 86 %

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 887MethanolLösungsmittel2×

Versuchsvorschrift

A mixture of 7.2 g (0.0227 mole) of 2,4,6-trinitro-1,3,5-trichlorobenzene and 70 ml of methanol was stirred in an ice bath while a solution of 9.9 g (0.162 mole) of ethanolamine in 70 ml of methanol was added over 10 min. Stirring at room temperature gave a solution from which yellow solid precipitated until the mixture became too thick to stir. After standing for 2 hr., the mixture was filtered to give 7.6 g (86%) of 2,4,6-trinitro-1,3,5-tris(2-hydroxyethylamino)benzene; 1H NMR (DMSO-d6): 3.48 (m, 6H), 3.72 (m, 6H).

Aufarbeitung

  1. additionwas added over 10 min
  2. customgave a solution from which yellow solid
  3. customprecipitated until the mixture
  4. stirringto stir
  5. filtration, the mixture was filtered

Quellen und Nachweise

ORD-Eintrag
ord-0490247fe1f142c6b0115b9e1b214b48
Quelldatensatz
uspto-grants-1992_01
Patentnummer
US05081255

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