Ammonia → 1-(3-mercapto-2-methylthio-1-oxopropyl)-4,4-dimethoxy-L-proline

HRID 1106070Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1106070
C([S:4][CH2:5][CH:6]([S:21][CH3:22])[C:7]([N:9]1[CH2:16][C:15]([O:19][CH3:20])([O:17][CH3:18])[CH2:14][C@H:10]1[C:11]([OH:13])=[O:12])=[O:8])(=O)C.N>>[SH:4][CH2:5][CH:6]([S:21][CH3:22])[C:7]([N:9]1[CH2:16][C:15]([O:19][CH3:20])([O:17][CH3:18])[CH2:14][C@H:10]1[C:11]([OH:13])=[O:12])=[O:8]

Komponenten

3

Edukt 2

HCID 222AmmoniaHCID 536836981-[3-(acetylthio)-2-methylthio-1-oxopropyl]-4,4-dimethoxy-L-proline

Produkt 1

HCID 540705831-(3-mercapto-2-methylthio-1-oxopropyl)-4,4-dimethoxy-L-proline

Versuchsvorschrift

The product from part (a) is hydrolyzed with concentrated ammonia according to the procedure of Example 4 to yield 1-(3-mercapto-2-methylthio-1-oxopropyl)-4,4-dimethoxy-L-proline.

Quellen und Nachweise

ORD-Eintrag
ord-cc033ea52898462fb3b29dcc17bdc8e0
Quelldatensatz
uspto-grants-1982_01
Patentnummer
US04311697

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