2-Octanol → Propan-2-yl 2-dodecylbenzene-1-sulfonate

HRID 1109090

Reaktionsgleichung

Reaktionsgleichung von HRID 1109090
CC(O)CCCCCC.[CH2:10]([C:22]1C=CC=C[C:23]=1S(Cl)(=O)=O)[CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19]CC.[C:32]1(C)[CH:37]=[CH:36][C:35]([S:38]([O:41][CH:42]([CH3:49])[CH2:43]CCCCC)(=[O:40])=[O:39])=[CH:34][CH:33]=1>>[CH2:19]([C:34]1[CH:33]=[CH:32][CH:37]=[CH:36][C:35]=1[S:38]([O:41][CH:42]([CH3:43])[CH3:49])(=[O:39])=[O:40])[CH2:18][CH2:17][CH2:16][CH2:15][CH2:14][CH2:13][CH2:12][CH2:11][CH2:10][CH2:22][CH3:23]

Komponenten

4

Edukt 3

HCID 200832-OctanolHCID 3912199HCID 3912199, VerbindungHCID 204390012-Dodecylbenzene-1-sulfonyl chloride

Produkt 1

HCID 23368822Propan-2-yl 2-dodecylbenzene-1-sulfonateAusbeute 83 %

Versuchsvorschrift

In the Example of preparation of material 18, 2-octanol was used in place of 2-propanol in the Example of preparation of material 17. In the Example of preparation of material 19, dodecylbenzene sulfonyl chloride was used in place of p-toluene sulfonyl chloride in the Example of preparation of material 17. Other procedures were made in the same way as the Example of preparation of material 17. In the Example of preparation of material 18, 1-methylheptyl p-toluene sulfonate was obtained in the yield of 72% and, in the Example of preparation of material 19, 1-methylethyl dodecylbenzene sulfonate was obtained in the yield of 83%.

Quellen und Nachweise

ORD-Eintrag
ord-fcde6d5423e74d30ae06c643be62027b
Quelldatensatz
uspto-grants-1994_06
Patentnummer
US05319024

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