HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
Formaldehyde → Dimethyl alpha-hydroxymethyl-alpha-fluoromalonate
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | Formaldehyde | HCID 712 | — |
| Edukt | Dimethyl fluoromalonate | HCID 2737111 | — |
| Produkt | Dimethyl alpha-hydroxymethyl-alpha-fluoromalonate | HCID 10910147 | — |
Reaktionsschritte
The process according to the invention for preparing an α-fluoroacrylic acid ester is carried out in three stages. First dimethyl α-fluoromalonate is reacted with formaldehyde to give dimethyl a-hydroxymethyl-α-fluoromalonate, which is then hydrolyzed and the hydrolysis product is dicarboxylated and dehydrated, and finally the resulting α-fluoroacrylic acid is esterified with an alcohol of the formula (3).
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US05319131 |
| Quelldatensatz | uspto-grants-1994_06 |
| ORD ID | ord-fca26e6d78084861ac2ddc1bf309c09d |
| Quellennotiz | uspto-grants-1994_06 |