5-Bromo-2-furanecarboxylic acid → 5-(3,7,11-Trimethyldodecyloxy)-2-furancarboxylic acid

HRID 1111415

Reaktionsgleichung

Reaktionsgleichung von HRID 1111415
[CH3:1][CH:2]([CH2:6][CH2:7][CH2:8][CH:9]([CH3:16])[CH2:10][CH2:11][CH2:12][CH:13]([CH3:15])[CH3:14])[CH2:3][CH2:4][OH:5].C(O)CCCCCCCCC/C=C\CC.Br[C:33]1[O:37][C:36]([C:38]([OH:40])=[O:39])=[CH:35][CH:34]=1.ClC1OC(C(O)=O)=CC=1>>[CH3:1][CH:2]([CH2:6][CH2:7][CH2:8][CH:9]([CH3:16])[CH2:10][CH2:11][CH2:12][CH:13]([CH3:15])[CH3:14])[CH2:3][CH2:4][O:5][C:33]1[O:37][C:36]([C:38]([OH:40])=[O:39])=[CH:35][CH:34]=1

Komponenten

5

Edukt 4

HCID 685115-Bromo-2-furanecarboxylic acidHCID 1388243,7,11-Trimethyl-1-dodecanolHCID 2348535-Chlorofuran-2-carboxylic acidHCID 1712010Cis-11-tetradecenol

Produkt 1

HCID 136560045-(3,7,11-Trimethyldodecyloxy)-2-furancarboxylic acid

Versuchsvorschrift

In the procedure of Example 4(A), 3,7,11-trimethyldodecanol was substituted for cis-11-tetradecenol and 5-bromo-2-furoic acid substituted for 5-chloro-2-furoic acid to yield 5-(3,7,11-trimethyldodecyloxy)-2-furancarboxylic acid, M.P. 70°-73° C.

Quellen und Nachweise

ORD-Eintrag
ord-b0569406b3da4d61be543274e2f21563
Quelldatensatz
uspto-grants-1990_12
Patentnummer
US04980371

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