p-Toluenesulfonic acid → Sodium 4-methylbenzenesulfonate

HRID 1112757

Reaktionsgleichung

Reaktionsgleichung von HRID 1112757
[N:1]1([CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][N:13]2[C:18](=[O:19])[CH2:17][O:16][CH2:15][C:14]2=[O:20])[CH2:6][CH2:5][CH2:4][CH2:3][CH2:2]1.[CH3:21][C:22]1[CH:23]=[CH:24][C:25]([S:28]([OH:31])(=[O:30])=[O:29])=[CH:26][CH:27]=1.[OH-].[Na+:33]>>[N:1]1([CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][NH:13][C:14](=[O:20])[CH2:15][O:16][CH2:17][C:18]([O-:29])=[O:19])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6]1.[Na+:33].[S:28]([C:25]1[CH:26]=[CH:27][C:22]([CH3:21])=[CH:23][CH:24]=1)([O-:31])(=[O:30])=[O:29].[Na+:33]

Komponenten

5

Edukt 3

HCID 6101p-Toluenesulfonic acid2×HCID 14798Sodium HydroxideHCID 12796195HCID 12796195, Verbindung2×

Produkt 2

HCID 3720192Sodium 4-methylbenzenesulfonateHCID 23686820HCID 23686820, Verbindung

Versuchsvorschrift

Preparation in situ from 4-(6-piperidinohexyl)-3,5-dioxomorpholine.p-toluenesulfonate. 43 milligrams (0.095 millimole) of 4-(6-piperidinohexyl)-3,5-dioxomorpholine.p-toluenesulfonate (prepared as described in Example IX) was dissolved in 2 milliliters of 0.1N sodium hydroxide (0.2 millimole) to obtain an aqueous solution of sodium [2-(6-piperidinohexyl)amino-2-oxoethoxy]acetate and sodium tosylate. The solution had the following spectral characteristics:

Quellen und Nachweise

ORD-Eintrag
ord-ac36745856d74bcdac67681dac197dd1
Quelldatensatz
uspto-grants-1978_10
Patentnummer
US04123538

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