Acetonitrile → 17-Ethyl-1-hydroxy-14-(tert-butyldimethylsiloxy)-12-[2'-(4"-hydroxy-3"-allyloxycyclohexyl)-1'-methylvinyl]-23,25-dimethoxy-13,19,21,27-tetramethyl-11,28-dioxa-4-azatricyclo[22.3.1.04,9]octacos-18-ene-2,3,10,16-tetraone

Reaktionsgleichung

[CH2:1]([CH3:2])[CH:3]1[C:4](=[O:72])[CH2:5][CH:6]([O:64][Si:65]([CH3:66])([CH3:67])[C:68]([CH3:69])([CH3:70])[CH3:71])[CH:7]([CH3:63])[CH:8]([C:42](=[CH:43][CH:44]2[CH2:45][CH:46]([O:58][CH2:59][CH:60]=[CH2:61])[CH:47]([O:50][Si:51]([C:52]([CH3:53])([CH3:54])[CH3:55])([CH3:56])[CH3:57])[CH2:48][CH2:49]2)[CH3:62])[O:9][C:10](=[O:41])[CH:11]2[CH2:12][CH2:13][CH2:14][CH2:15][N:16]2[C:17](=[O:40])[C:18](=[O:39])[C:19]2([OH:38])[CH:20]([CH3:37])[CH2:21][CH:22]([O:35][CH3:36])[CH:23]([CH:24]([O:32][CH3:33])[CH2:25][CH:26]([CH3:31])[CH2:27][C:28]([CH3:30])=[CH:29]1)[O:34]2.[CH3:74][C:75]#[N:76].[CH3:77][CH2:78][O:79][C:80](=[O:81])[CH3:82].[FH:73]>>[CH2:1]([CH3:2])[CH:3]1[C:4](=[O:72])[CH2:5][CH:6]([O:64][Si:65]([CH3:66])([CH3:67])[C:68]([CH3:69])([CH3:70])[CH3:71])[CH:7]([CH3:63])[CH:8]([C:42](=[CH:43][CH:44]2[CH2:45][CH:46]([O:58][CH2:59][CH:60]=[CH2:61])[CH:47]([OH:50])[CH2:48][CH2:49]2)[CH3:62])[O:9][C:10](=[O:41])[CH:11]2[CH2:12][CH2:13][CH2:14][CH2:15][N:16]2[C:17](=[O:40])[C:18](=[O:39])[C:19]2([OH:38])[CH:20]([CH3:37])[CH2:21][CH:22]([O:35][CH3:36])[CH:23]([CH:24]([O:32][CH3:33])[CH2:25][CH:26]([CH3:31])[CH2:27][C:28]([CH3:30])=[CH:29]1)[O:34]2