Reaktionsgleichung
[CH:1]1[C:10]2[C:5](=[CH:6][CH:7]=[CH:8][CH:9]=2)[CH:4]=[CH:3][C:2]=1[SH:11].[CH2:12]([O-])[CH2:13][CH3:14].[Na+].C(O)CC>>[CH2:12]([S:11][C:2]1[CH:3]=[CH:4][C:5]2[C:10](=[CH:9][CH:8]=[CH:7][CH:6]=2)[CH:1]=1)[CH2:13][CH3:14]Komponenten
4
Versuchsvorschrift
50 g (0.31 mole) of naphth-2-yl mercaptan were introduced into a solution of 29.5 g (0.36 mole) of sodium n-propanolate and 800 ml (10.6 moles) of n-propanol, and the mixture was heated from 25° to 150° C. in the course of 60 minutes under a carbon monoxide pressure of 300 bar in a 1.2 liter stirred autoclave, and then kept at this temperature for 10 hours. The mixture which emerged from the reactor was distilled to give 58.8 g (95% of theory) of naphth-2-yl n-propyl thioether of boiling point 115°-120° C./0.6 mbar.
Aufarbeitung
- temperaturethe mixture was heated from 25° to 150° C. in the course of 60 minutes under a carbon monoxide pressure of 300 bar in a 1.2 liter
- distillationwas distilled
Quellen und Nachweise
- ORD-Eintrag
- ord-07d14be4db0c4bb3b2e556d34dfbff5e
- Quelldatensatz
- uspto-grants-1984_12
- Patentnummer
- US04490558
Verknüpfte Notizen
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