Hexane → HCID 178511346, Verbindung

HRID 1155647

Reaktionsgleichung

Reaktionsgleichung von HRID 1155647
[NH2:1][CH2:2][CH2:3][NH:4][CH2:5][CH2:6][NH:7][CH2:8][CH2:9][NH:10][CH2:11][CH2:12][NH2:13].C1([CH:20]([CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH3:39])[C:21](O)=[O:22])C=CC=CC=1.[CH3:40][CH2:41][CH2:42][CH2:43][CH2:44][CH3:45]>>[C:42]1([CH2:39][CH2:38][CH2:37][CH2:36][CH2:35][CH2:34][CH2:33][CH2:32][CH2:31][CH2:30][CH2:29][CH2:28][CH2:27][CH2:26][CH2:25][CH2:24][CH2:20][C:21]([NH-:1])=[O:22])[CH:41]=[CH:40][CH:45]=[CH:44][CH:43]=1.[C:42]1([CH2:39][CH2:38][CH2:37][CH2:36][CH2:35][CH2:34][CH2:33][CH2:32][CH2:31][CH2:30][CH2:29][CH2:28][CH2:27][CH2:26][CH2:25][CH2:24][CH2:20][C:21]([NH-:1])=[O:22])[CH:41]=[CH:40][CH:45]=[CH:44][CH:43]=1.[C:42]1([CH2:39][CH2:38][CH2:37][CH2:36][CH2:35][CH2:34][CH2:33][CH2:32][CH2:31][CH2:30][CH2:29][CH2:28][CH2:27][CH2:26][CH2:25][CH2:24][CH2:20][C:21]([NH-:1])=[O:22])[CH:41]=[CH:40][CH:45]=[CH:44][CH:43]=1.[NH2:13][CH2:12][CH2:11][NH:10][CH2:9][CH2:8][NH:7][CH2:6][CH2:5][NH:4][CH2:3][CH2:2][NH2:1]

Komponenten

4

Edukt 3

HCID 8058Hexane2×HCID 8197TetraethylenepentamineHCID 220152372-Phenyloctadecanoic acid2×

Produkt 1

HCID 178511346HCID 178511346, Verbindung

Reaktionsbedingungen

Temperatur
175 °C

Versuchsvorschrift

Into a 300 ml reaction flask equipped with a thermometer, an agitator and an addition funnel, 6 g (0.03 mole) tetraethylenepentamine was added and heated to 70°-75° C. with agitation. From the addition funnel, 32.4 g (0.09 mole) phenylstearic acid was added over 10 minutes. To insure complete addition of phenylstearic acid, 15-20 ml hexane was added to the addition funnel and thence into the reaction mixture after hexane was allowed to evaporate away, the contents of the flask was placed under reduced pressure and heated to 175° C. with agitation. Heating was continued at 175° C. for 2 hours allowing the condensation water to distill off. The product, tetraethylenepentamine tris(phenylstearoylamide) was viscous, amber colored liquid.

Aufarbeitung

  1. customInto a 300 ml reaction flask
  2. customequipped with a thermometer
  3. temperatureheated to 70°-75° C. with agitation
  4. customto evaporate away
  5. temperatureHeating
  6. customthe condensation water
  7. distillationto distill off

Quellen und Nachweise

ORD-Eintrag
ord-f8fe0ca93e4d48659534eb6651c3c68e
Quelldatensatz
uspto-grants-1982_06
Patentnummer
US04332737

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