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HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
HRID 1156090Erstellt: 24. Oktober 2026

Benzoic Acid → Benzoic acid, 4-(1,1-dimethylethyl)-, hydrazide

https://huagongshe.com/de/reaction/1156090

Reaktionsgleichung

Beteiligte Stoffe

RolleNameHCIDEinwaage
EduktBenzoic AcidHCID 243—
Edukt4-tert-Butylbenzoic acidHCID 7403—
EduktHydrazineHCID 9321—
Edukt2-Hydroxy-1-naphthaldehyde-o-aminobenzoyl hydrazoneHCID 3084951—
ProduktBenzoic acid, 4-(1,1-dimethylethyl)-, hydrazideHCID 123513—

Reaktionsschritte

The particularly preferred substituted aromatic hydrazone 2-hydroxy-1-naphthaldehyde-p-(t-butyl)-benzoyl hydrazone is prepared in a manner similar to the preparation of 2-hydroxy-1-naphthaldehyde-o-aminobenzoyl hydrazone, Equations (1) through (3) above. Since the ester of p-(t-butyl)-benzoic acid is not available the preparation of this hydrazone requires the additional step of esterification of the benzoic acid. The ester of p-(t-butyl)-benzoic acid is reacted with hydrazine to produce p-(t-butyl)-benzhydrazide. This hydrazide is then reacted with 2-hydroxy-1-naphthaldehyde to yield 2-hydroxy-1-naphthaldehyde-p-(t-butyl)-benzoyl hydrazone.

Herkunft & Nachweise

DOI10.6084/m9.figshare.5104873.v1
PatentnummerUS04334015
Quelldatensatzuspto-grants-1982_06
ORD IDord-803e2f836c27437cbbaca2d01beb8325
Quellennotizuspto-grants-1982_06