Triethylamine → 1-(p-CHLOROPHENYLSULFONYL)VINYL PHENYL SULFIDE

HRID 1156387Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1156387
[C:1]1([S:7][CH:8]([S:11]([C:14]2[CH:19]=[CH:18][C:17]([Cl:20])=[CH:16][CH:15]=2)(=[O:13])=[O:12])[CH2:9]Cl)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.C(N(CC)CC)C>O1CCCC1>[C:1]1([S:7][C:8]([S:11]([C:14]2[CH:15]=[CH:16][C:17]([Cl:20])=[CH:18][CH:19]=2)(=[O:13])=[O:12])=[CH2:9])[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=1

Komponenten

4

Edukt 2

HCID 8471TriethylamineHCID 130447952-CHLORO-1-(p-CHLOROPHENYLSULFONYL)ETHYL PHENYL SULFIDE

Produkt 1

HCID 205359981-(p-CHLOROPHENYLSULFONYL)VINYL PHENYL SULFIDE

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 8028TetrahydrofuranLösungsmittel

Versuchsvorschrift

To a solution of 30 g (86.5 mmoles) of 2-chloro-1-(p-chlorophenylsulfonyl)ethyl phenyl sulfide in 100 ml of tetrahydrofuran was added 12.2 ml (8.88 g, 87.8 mmoles) of triethylamine. After two hours the reaction mixture was filtered to remove triethylamine hydrochloride. The filtrate was evaporated down under reduced pressure, first at 15 mm and finally at 0.01 mm (25° C.), to give a light yellow oil.

Aufarbeitung

  1. filtrationAfter two hours the reaction mixture was filtered
  2. customto remove triethylamine hydrochloride
  3. customThe filtrate was evaporated down under reduced pressure, first at 15 mm and finally at 0.01 mm (25° C.)
  4. customto give a light yellow oil

Quellen und Nachweise

ORD-Eintrag
ord-f6709858b81d4de18b23bf71e816d299
Quelldatensatz
uspto-grants-1982_06
Patentnummer
US04335142

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