(1aS,7bS)-2,2-Dimethyl-1a,7b-dihydro-2H-oxireno[2,3-c]chromene-6-carbonitrile → HCID 178431177, Verbindung
Reaktionsgleichung
[CH3:1][C:2]1([CH3:15])[O:11][C:10]2[C:5](=[CH:6][C:7]([C:12]#[N:13])=[CH:8][CH:9]=2)[C@@H:4]2[O:14][C@H:3]12.[Cl:16][C:17]1[CH:26]=[CH:25][C:20]2[NH:21][C:22]([SH:24])=[N:23][C:19]=2[CH:18]=1>>[Cl:16][C:17]1[CH:26]=[CH:25][C:20]2[NH:21][C:22]([S:24][C@@H:4]3[C:5]4[C:10](=[CH:9][CH:8]=[C:7]([C:12]#[N:13])[CH:6]=4)[O:11][C:2]([CH3:15])([CH3:1])[C@@H:3]3[OH:14])=[N:23][C:19]=2[CH:18]=1Komponenten
3
Versuchsvorschrift
Following the procedure in Example 1, using (S,S)-2,2-dimethyl-1a,7b-dihydro-2H-1,3-dioxa-cyclopropa[a]naphthalene-6-carbonitrile and 5-chloro-1H-benzoimidazole-2-thiol as starting material, the title compound was prepared as a white solid.
Quellen und Nachweise
- ORD-Eintrag
- ord-a61a5cb70a8048c88180c5a9e5b6a9a9
- Quelldatensatz
- uspto-grants-2010_10
- Patentnummer
- US07812183B2
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