(2,6-Dimethylphenyl)hydrazine → Benzene, 1,1'-tellurobis[4-methoxy-

HRID 1164702Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1164702
CC1C=CC=C(C)C=1NN.[CH3:11][O:12][C:13]1[CH:18]=[CH:17][C:16]([Te:19]([C:21]2[CH:26]=[CH:25][C:24]([O:27][CH3:28])=[CH:23][CH:22]=2)=O)=[CH:15][CH:14]=1>C1(C)C=CC=C(C)C=1>[CH3:28][O:27][C:24]1[CH:23]=[CH:22][C:21]([Te:19][C:16]2[CH:17]=[CH:18][C:13]([O:12][CH3:11])=[CH:14][CH:15]=2)=[CH:26][CH:25]=1

Komponenten

4

Edukt 2

HCID 408103(2,6-Dimethylphenyl)hydrazineHCID 3044917Bis(p-methoxyphenyl) telluroxide

Produkt 1

HCID 4605422Benzene, 1,1'-tellurobis[4-methoxy-Ausbeute 74 %

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 7929M-XyleneLösungsmittel

Versuchsvorschrift

2,6-Dimethylphenylhydrazine (68 mg, 0.50 mmol) was reacted with bis-(p-methoxyphenyl)-telluroxide for 0.2 h. to yield m-xylene (70%, p.l.c. (benzene-petroleum ether 1:1) afforded bis-(p-methoxyphenyl)-telluride (126 mg, 74%) and what appears to be 2,6-dimethylphenyl-4-methoxyphenyl-telluride as a colourless oil, m/e 342 (M+, 100%), 234, 212, 197, 105, 104, 79, 77, and 77.

Quellen und Nachweise

ORD-Eintrag
ord-f5eaa9392b2b4616944dbf8fd37af27b
Quelldatensatz
uspto-grants-1983_01
Patentnummer
US04370497

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