Isopropanol → 2-Methoxycyclohexanone
Reaktionsgleichung
CC[C@@H]1[C@@H]2C[C@@H]([C@H](O)C3[C:21]4[C:16](=[CH:17][CH:18]=[CH:19][CH:20]=4)N=CC=3)N(CC2)C1.[OH-:23].[K+].[CH:25]([OH:28])(C)C>>[CH3:25][O:28][CH:16]1[CH2:17][CH2:18][CH2:19][CH2:20][C:21]1=[O:23]Komponenten
4
Versuchsvorschrift
Example 1 is repeated, except that isopropanol is used as solvent, 10 mg of hydrocinchonidine are used as modifier and 100 mg of catalyst are used. In addition, 7 mg of KOH are added. The yield is 0.75 g of product of 90% purity containing 10% solvent (88%).
Quellen und Nachweise
- ORD-Eintrag
- ord-e010689b0f104091b8a740251dbe85ca
- Quelldatensatz
- uspto-grants-2003_09
- Patentnummer
- US06617475B2
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