3,3'-(1,1,3,3-Tetramethyldisiloxane-1,3-diyl)bispropylamine → Tetramethylammonium 3-aminopropyldimethylsilanolate

HRID 1184974

Reaktionsgleichung

Reaktionsgleichung von HRID 1184974
[NH2:1][CH2:2][CH2:3][CH2:4][Si:5]([CH3:15])([CH3:14])[O:6][Si](C)(C)CCCN.O.O.O.O.O.[OH-].[CH3:22][N+:23]([CH3:26])([CH3:25])[CH3:24]>O1CCCC1>[NH2:1][CH2:2][CH2:3][CH2:4][Si:5]([CH3:15])([CH3:14])[O-:6].[CH3:22][N+:23]([CH3:26])([CH3:25])[CH3:24]

Komponenten

4

Edukt 2

HCID 171813,3'-(1,1,3,3-Tetramethyldisiloxane-1,3-diyl)bispropylamineHCID 82620Tetramethylammonium Hydroxide Pentahydrate

Produkt 1

HCID 11769672Tetramethylammonium 3-aminopropyldimethylsilanolate

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 8028TetrahydrofuranLösungsmittel

Versuchsvorschrift

A 250 ml three-neck round-bottom flask equipped with a magnetic stirrer, argon inlet, and condenser with drying tube was charged with 12.4 g (0.05 mol) of 1,3-bis(3-aminopropyl)tetramethyldisiloxane, 18.1 (88.12 mmol) of tetramethylammonium hydroxide pentahydrate, and 30 ml of tetrahydrofuran. The mixture was heated under reflux in an inert gas atmosphere for 5 hours.

Aufarbeitung

  1. customA 250 ml three-neck round-bottom flask equipped with a magnetic stirrer, argon inlet, and condenser
  2. customwith drying tube
  3. temperatureThe mixture was heated
  4. temperatureunder reflux in an inert gas atmosphere for 5 hours

Quellen und Nachweise

ORD-Eintrag
ord-7dc387a01e5b4d048a661473a2b2e2b4
Quelldatensatz
uspto-grants-2014_03
Patentnummer
US08669388B2

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