HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
(Nitromethyl)benzene → 6-Nitro-6-phenylhex-5-enal
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | (Nitromethyl)benzene | HCID 69321 | — |
| Edukt | Pentanal, 5,5-dimethoxy- | HCID 170903 | — |
| Lösungsmittel | Ethyl acetate hexane | HCID 21226206 | — |
| Produkt | 6-Nitro-6-phenylhex-5-enal | HCID 76552940 | 41,1% |
Reaktionsschritte
Prepared according to the general procedure B from 1-(nitromethyl)benzene 112d (24 mmol) and 5,5-dimethoxypentanal 131 (16 mmol) to provide the title compound as yellow oil (E/Z=6.7/1) (1.44 g, 41% yield) after silica gel chromatography (EtOAc/Hexane).
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US08680335B2 |
| Quelldatensatz | uspto-grants-2014_03 |
| ORD ID | ord-088268a327994039bea3fca27f7f92b0 |
| Quellennotiz | uspto-grants-2014_03 |