HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
Pentanal, 5,5-dimethoxy- → (E)-6-nitro-7-p-tolylhept-5-enal
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | Pentanal, 5,5-dimethoxy- | HCID 170903 | — |
| Edukt | 1-Methyl-4-(2-nitroethyl)benzene | HCID 11228988 | — |
| Lösungsmittel | Ethyl acetate hexane | HCID 21226206 | — |
| Produkt | (E)-6-nitro-7-p-tolylhept-5-enal | HCID 58434561 | 35% |
Reaktionsschritte
Prepared according to the general procedure B from 1-methyl-4-(2-nitroethyl)benzene 112f (24 mmol) and 5,5-dimethoxypentanal 131 (16 mmol) to provide the title compound as yellow oil (1.38 g, 35% yield) after silica gel chromatography (EtOAc/Hexane).
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US08680335B2 |
| Quelldatensatz | uspto-grants-2014_03 |
| ORD ID | ord-2d70649003f54a99891b9c95a32471c4 |
| Quellennotiz | uspto-grants-2014_03 |