3',4',5'-Trimethoxyacetophenone → 3-(4-Hydroxy-3-methoxy-5-nitrophenyl)-1-(3,4,5-trimethoxyphenyl)prop-2-en-1-one

HRID 1195964

Reaktionsgleichung

Reaktionsgleichung von HRID 1195964
[OH:1][C:2]1[C:9]([N+:10]([O-:12])=[O:11])=[CH:8][C:5]([CH:6]=O)=[CH:4][C:3]=1[O:13][CH3:14].[CH3:15][O:16][C:17]1[CH:18]=[C:19]([C:27](=[O:29])[CH3:28])[CH:20]=[C:21]([O:25][CH3:26])[C:22]=1[O:23][CH3:24]>>[OH:1][C:2]1[C:9]([N+:10]([O-:12])=[O:11])=[CH:8][C:5]([CH:6]=[CH:28][C:27]([C:19]2[CH:20]=[C:21]([O:25][CH3:26])[C:22]([O:23][CH3:24])=[C:17]([O:16][CH3:15])[CH:18]=2)=[O:29])=[CH:4][C:3]=1[O:13][CH3:14]

Komponenten

3

Edukt 2

HCID 143453',4',5'-TrimethoxyacetophenoneHCID 811345-Nitrovanillin

Produkt 1

HCID 34301783-(4-Hydroxy-3-methoxy-5-nitrophenyl)-1-(3,4,5-trimethoxyphenyl)prop-2-en-1-one

Versuchsvorschrift

The procedure described in Example 8 was repeated by using 2.0 g of 4-hydroxy-3-methoxy-5-nitrobenzaldehyde and 2.1 g of 3',4',5'-trimethoxyacetophenone. Yield 2.2 g (57%), m.p. 123°-125° C.

Quellen und Nachweise

ORD-Eintrag
ord-558a33cba7124c36b52fb7324928c1c1
Quelldatensatz
uspto-grants-1992_05
Patentnummer
US05112861

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