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HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
HRID 1197912Erstellt: 26. Oktober 2026

Benzidine → 2-Phenylquinoxaline

https://huagongshe.com/reaction/1197912

Reaktionsgleichung

Beteiligte Stoffe

RolleNameHCIDEinwaage
EduktBenzidineHCID 7111—
Edukt3,3'-DihydroxybenzidineHCID 16918—
Edukt3,4-Diaminobenzoic acidHCID 69263—
Edukt4,5-Diaminophthalic acidHCID 19105448—
Produkt2-PhenylquinoxalineHCID 78725—

Reaktionsschritte

One proceeds in accordance with Example 1, where in place of 3,4-diaminobenzoic acid, 4,5-diaminophthalic acid is used, and in place of 3,3'-dihydroxy-4,4'-diaminobiphenyl, 4.4'- diaminobiphenyl is used. Via tetracarboxylic acid, or the corresponding acid chloride, as an intermediate stage, a copolymer with phenylquinoxaline units and o-carboxyamide groupings (-CO-NH-) is thereby obtained. When annealed to approximately 400° C., they cyclize into imide structures.

Herkunft & Nachweise

DOI10.6084/m9.figshare.5104873.v1
PatentnummerUS05278277
Quelldatensatzuspto-grants-1994_01
ORD IDord-154d779a13a44ad69320c66de37f660d
Quellennotizuspto-grants-1994_01