HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
HRID 1198213Erstellt: 24. Oktober 2026
Ethyl Acetoacetate → Ethyl 2Z-[(4-hexylphenyl)methylene]-3-oxobutanoate
https://huagongshe.com/de/reaction/1198213
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|
| Edukt | Ethyl Acetoacetate | HCID 8868 | — |
| Edukt | Benzaldehyde, 4-hexyl- | HCID 170813 | — |
| Katalysator | Piperidine | HCID 8082 | — |
| Produkt | Ethyl 2Z-[(4-hexylphenyl)methylene]-3-oxobutanoate | HCID 67820812 | — |
Reaktionsschritte
Ethyl acetoacetate (3.9g, 0.03 moles), parahexylbenzaldehyde (3.8g, 0.02 moles) and piperidine (3 drops) were stirred at room temperature for 20 hrs. and then stirred for 4 days at 70° C. Products A and B were separated and purified by silica gel chromatography. Structure assignments were supported by NMR, infrared and uv spectra and elemental analysis (302.4).
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| Patentnummer | US05280047 |
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| Quelldatensatz | uspto-grants-1994_01 |
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| ORD ID | ord-aa282224ed5b4f9c861e2e466cf56d88 |
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| Quellennotiz | uspto-grants-1994_01 |
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