Acetyl chloride → 4,4-Dinitrobutyl acetate

HRID 1199508Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1199508
[N+:1]([CH:4]([N+:9]([O-:11])=[O:10])[CH2:5][CH2:6][CH2:7][OH:8])([O-:3])=[O:2].[C:12](Cl)(=[O:14])[CH3:13]>C(Cl)Cl>[C:12]([O:8][CH2:7][CH2:6][CH2:5][CH:4]([N+:9]([O-:11])=[O:10])[N+:1]([O-:3])=[O:2])(=[O:14])[CH3:13]

Komponenten

4

Edukt 2

HCID 6367Acetyl chlorideHCID 144017664,4-Dinitrobutan-1-ol

Produkt 1

HCID 144017674,4-Dinitrobutyl acetate

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 6344DichloromethaneLösungsmittel

Versuchsvorschrift

This ester was synthesized by treating a solution of 4,4-dinitro-1-butanol (39.2 g, 0.24 mols) in CH2Cl2 (100 ml) with acetyl chloride (22 ml, 24 g, 0.31 mol). After 90 minutes at room temperature, the reaction was quenched with ice water. Separation, drying (MgSO4), and concentration of the organic phase gave the product (42.7 g, 87%) as a light yellow oil; nD =1.4574 (24C). The infrared spectrum of the product had peaks at 2960, 1745, 1575, 1245, and 1060 cm-1. Elemental analyses-Calculated for C6H10N2O6 : C, 34.95; H, 4.85; N, 13.59; Found: C, 35.17; H, 4.83; N, 12.95.

Aufarbeitung

  1. customthe reaction was quenched with ice water
  2. customSeparation
  3. dry with materialdrying (MgSO4), and concentration of the organic phase

Quellen und Nachweise

ORD-Eintrag
ord-cf1ae0a1194d4a8491da65d770a89a86
Quelldatensatz
uspto-grants-1990_02
Patentnummer
US04900851

Notizen zur Reaktion

Wird geladen…