Aniline → 6-Amino-2-(aminomethyl)-3-methoxybenzene-1-sulfonic acid

HRID 1249323

Reaktionsgleichung

Reaktionsgleichung von HRID 1249323
[NH2:1][C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[NH2:8][C:9]1C=C(Cl)C=CC=1Cl.NC1C=C(C)C=CC=1C.NC1C([O:33][CH3:34])=CC=C(C)C=1.NC1C=CC([N+]([O-])=O)=CC=1OC.NC1(C2C=CC=CC=2)C=CC=CC1.C1C=CC(OC2C(N)=CC=CC=2)=CC=1.NC1C=CC(C)=CC=1[S:83]([OH:86])(=[O:85])=[O:84].NC1C(S(O)(=O)=O)=CC=C(C)C=1.NC1C2C(=CC=CC=2)C=CC=1.NC1C=CC2C(=CC=CC=2)C=1.NC1C2C=C(S(O)(=O)=O)C=C(S(O)(=O)=O)C=2C=CC=1S(O)(=O)=O>>[NH2:1][C:2]1[C:7]([S:83]([OH:86])(=[O:85])=[O:84])=[C:6]([CH2:9][NH2:8])[C:5]([O:33][CH3:34])=[CH:4][CH:3]=1

Komponenten

13

Edukt 12

HCID 6115AnilineHCID 69342-Amino-5-methylbenzenesulfonic acidHCID 70572-NaphthylamineHCID 72592,5-DimethylanilineHCID 72622,5-DichloroanilineHCID 73372-Methoxy-4-nitroanilineHCID 84452-Methoxy-5-MethylanilineHCID 86401-NaphthylamineHCID 666222-Amino-4-methylbenzenesulfonic acidHCID 75899Benzenamine, 2-phenoxy-HCID 149931755-Aminonaphthalene-1,3,6-trisulfonic acidHCID 187982041-Aminobiphenyl

Produkt 1

HCID 226169446-Amino-2-(aminomethyl)-3-methoxybenzene-1-sulfonic acid

Versuchsvorschrift

If both radicals --N(R1)--X1 and --N(R2)--X2 in formula (1) are attached to the same component, e.g. the coupling component, as described above, it is also possible to use as diazo components those which do not contain an acylatable amino group in addition to the amino group to be diazotised. Examples of such diazo components are: aminobenzene, 1-amino-2-, -3- or -4-methylbenzene, 1-amino-2-, -3- or -4-methoxybenzene, 1-amino-2-, -3- or -4-chlorobenzene, 1-amino-2,5-dichlorobenzene, 1-amino-2,5-dimethylbenzene, 1-amino-3-methyl-6-methoxybenzene, 1-amino-2-methoxy-4-nitrobenzene, 1-aminobiphenyl, 1-aminobenzene-2-, -3- or -4-carboxylic acid, 2-aminodiphenyl ether, 1-aminobenzene-2-, -3- or -4-sulfonamide, 1-aminobenzene-2-, -3- or -4-sulfonic acid, 1-aminobenzene-2,4- and -2,5-disulfonic acid, 1-amino-4-methylbenzene-2-sulfonic acid, 1-amino-3-methylbenzene-6 -sulfonic acid, 1-amino-6-methylbenzene-3- or -4-sulfonic acid, 1-aminonaphthalene, 2-aminonaphthalene, 1-aminonaphthalene-2-, -4-, -5-, -6-, -7- or -8-sulfonic acid, 2-aminonaphthalene-1-, -3-, -4-, -5-, -6-, -7- or -8-sulfonic acid, 1-aminonaphthalene-3,6- or -5,7-disulfonic acid, 2-aminonaphthalene-1,5-, -1,7-, -3,6-, -5,7- 4,8- or -6,8-disulfonic acid, 1-aminonaphthalene-2,5,7-trisulfonic acid, 2-aminonaphthalene-1,5,7-, -3,6,8- or -4,6,8-trisulfonic acid, 4-aminobenzene-3,4'-disulfonic acid, 3-methoxy-4-amino-6-methylazobenzene-2',4'-disulfonic acid or 3-methoxy-4-amino-6-methylazobenzene-2',5'-disulfonic acid.

Aufarbeitung

  1. additionin addition to the amino group

Quellen und Nachweise

ORD-Eintrag
ord-866b633e3e844bf69208ef05419318b9
Quelldatensatz
uspto-grants-1986_12
Patentnummer
US04631065

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