Picolinic acid → Diethyl 2-(6-chloro-5-methylpyridin-3-yl)malonate

Reaktionsgleichung

[Br:1][c:2]1[cH:3][c:4]([CH3:9])[c:5]([Cl:8])[n:6][cH:7]1.[C:10](=[O:11])([O-:12])[O-:13].[C:25]([CH2:26][C:27](=[O:28])[O:29][CH2:30][CH3:31])(=[O:32])[O:33][CH2:34][CH3:35].[Cs+:14].[Cs+:15].[Cu:36][I:37].[n:16]1[cH:17][cH:18][cH:19][cH:20][c:21]1[C:22]([OH:23])=[O:24]>>[c:2]1([CH:26]([C:25](=[O:32])[O:33][CH2:34][CH3:35])[C:27](=[O:28])[O:29][CH2:30][CH3:31])[cH:3][c:4]([CH3:9])[c:5]([Cl:8])[n:6][cH:7]1

Komponenten

Edukt 6

HCID 1018Picolinic acid

HCID 7761Diethyl Malonate

HCID 19660Carbonate Ion

HCID 24350Copper(1+) iodide; Copper(I) iodide; Cuprous iodide; Cuprous iodide (CuI)

HCID 104967Cesium cation2×

HCID 2854345-Bromo-2-chloro-3-methylpyridine

Produkt 1

Quellen und Nachweise

ORD-Eintrag: ord-20bdddcccb1a4f199e6b92a674e1607e
Quelldatensatz: Training data from https://doi.org/10.1039/C8SC04228D (2/10)
DOI: 10.1039/C8SC04228D

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