1-[3-Methoxy-5-(pentafluorosulfanyl)phenyl]ethanone → 1-[3-Bromo-5-(pentafluorosulfanyl)phenyl]ethanone

HRID 1258525Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1258525
[Br:1][C:2]1[CH:3]=[C:4]([CH:11]=[C:12]([S:14]([F:19])([F:18])([F:17])([F:16])[F:15])[CH:13]=1)[C:5](N(OC)C)=[O:6].[CH3:20]OC1C=C(C(=O)C)C=C(S(F)(F)(F)(F)F)C=1>>[Br:1][C:2]1[CH:3]=[C:4]([C:5](=[O:6])[CH3:20])[CH:11]=[C:12]([S:14]([F:19])([F:18])([F:17])([F:16])[F:15])[CH:13]=1

Komponenten

3

Edukt 2

HCID 441831181-[3-Methoxy-5-(pentafluorosulfanyl)phenyl]ethanoneHCID 581374643-Bromo-N-methoxy-N-methyl-5-(pentafluorosulfanyl)benzamide

Produkt 1

HCID 581374301-[3-Bromo-5-(pentafluorosulfanyl)phenyl]ethanone

Versuchsvorschrift

3-Bromo-N-methoxy-N-methyl-5-(pentafluorosulfanyl)benzamide (1.1 g) was converted and worked up analogously to 21d). Purification by means of HPLC was not necessary. 935 mg of the title compound were obtained.

Aufarbeitung

  1. customPurification by means of HPLC

Quellen und Nachweise

ORD-Eintrag
ord-0638a360c6e0479685fe10f5a85c7df0
Quelldatensatz
uspto-grants-2013_06
Patentnummer
US08466169B2

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