HCID 57701082, Verbindung → HCID 57701075, Verbindung
Reaktionsgleichung
C([O:8][C:9]1[CH:14]=[CH:13][C:12]([C:15]2([C:22]3[CH:27]=[CH:26][CH:25]=[CH:24][C:23]=3[F:28])[CH2:20][CH2:19][CH2:18][CH2:17][C:16]2=[O:21])=[CH:11][CH:10]=1)C1C=CC=CC=1.FC1C=CC=CC=1C1(C2C=CC(O)=CC=2)CCCCCC1=O>>[F:28][C:23]1[CH:24]=[CH:25][CH:26]=[CH:27][C:22]=1[C:15]1([C:12]2[CH:11]=[CH:10][C:9]([OH:8])=[CH:14][CH:13]=2)[CH2:20][CH2:19][CH2:18][CH2:17][C:16]1=[O:21]Komponenten
3
Versuchsvorschrift
The title compound 21 was synthesized from compound 19 (5 mg) using the procedure described for the synthesis of compound 20. Yield: 3 mg. 1H-NMR (400 MHz, CDCl3): δ ppm 7.16-7.06 (m, 3H), 6.97 (ddd, J=11.76, 8.14, 1.28 Hz, 1H), 6.90-6.73 (m, 3H), 6.31 (dt, J=7.87, 7.86, 1.74 Hz, 1H), 4.92 (s, 1H), 2.69-2.40 (m, 2H), 2.41-2.23 (m, 2H), 1.95-1.82 (m, 2H), 1.83-1.69 (m, 2H).
Quellen und Nachweise
- ORD-Eintrag
- ord-3ab546c37c374f52ad79d7318b90e6a8
- Quelldatensatz
- uspto-grants-2013_06