HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
HRID 1270664Erstellt: 25. Oktober 2026
Tricyclohexylphosphine → 5-Butylnorbornene 5-norbornene-2-carboxylic acid butyl ester 5-norbornene-2-carboxylic acid methyl ester
https://huagongshe.com/reaction/1270664
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|
| Edukt | Tricyclohexylphosphine | HCID 75806 | — |
| Edukt | Bicyclo[2.2.1]hept-2-ene, 5-butyl- | HCID 168020 | — |
| Edukt | Methyl bicyclo[2.2.1]hept-5-ene-2-carboxylate | HCID 250075 | — |
| Edukt | N,N-dimethylanilinium tetrakis(pentafluorophenyl)borate | HCID 10996402 | — |
| Edukt | Butyl bicyclo[2.2.1]hept-5-ene-2-carboxylate | HCID 15608148 | — |
| Katalysator | palladium(II) acetate | HCID 167845 | — |
| Lösungsmittel | Toluene | HCID 1140 | — |
| Produkt | 5-Butylnorbornene 5-norbornene-2-carboxylic acid butyl ester 5-norbornene-2-carboxylic acid methyl ester | HCID 86600019 | — |
Reaktionsschritte
5-Butylnorbornene (9.8 kg), 5-norbornene-2-carboxylic acid butyl ester (8.5 kg) and 5-norbornene-2-carboxylic acid methyl ester (16.7 kg) were added to a reactor at room temperature. Toluene (26.3 kg) was added to the reactor. Air inside the reactor was replaced by nitrogen and the reactor was heated to 90° C. Palladium diacetate (6.2 g), dimethyl aniliniumtetrakis (pentafluorophenyl)borate (44.1 g) and tricylcohexylphosphine (7.7 g) dissolved in dichloromethyl were added to the reactor. Reaction was performed for 18 hours while stirring to obtain a tricopolymer solution comprising 30 mol % of 5-butylnorbornene, 20 mol % of 5-norbornene-2-carboxylic acid butyl ester and 50 mol % of 5-norbornene-2-carboxylic acid methyl ester monomers. 43.9 kg of toluene was added to dilute the solution.
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| Patentnummer | US07202312B2 |
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| Quelldatensatz | uspto-grants-2007_04 |
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| ORD ID | ord-7d9d09ca1ae54b189c048f595094b186 |
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| Quellennotiz | uspto-grants-2007_04 |
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