Aluminium lithium hydride → HCID 69360623, Verbindung
Reaktionsgleichung
[CH3:1][C@H:2]1[N:14]2[C:6](=[CH:7][C:8]3[C:13]2=[N:12][CH:11]=[C:10]([CH3:15])[CH:9]=3)[C:5](=O)[NH:4][CH2:3]1.[H-].[Al+3].[Li+].[H-].[H-].[H-]>>[CH3:1][C@H:2]1[N:14]2[C:6](=[CH:7][C:8]3[C:13]2=[N:12][CH:11]=[C:10]([CH3:15])[CH:9]=3)[CH2:5][NH:4][CH2:3]1Komponenten
3
Versuchsvorschrift
This compound was prepared in analogy to Example 3, intermediate l) from (R)-4,7-dimethyl-3,4-dihydro-2H-2,4a,5-triaza-fluoren-1-one and lithium aluminium hydride. The product was purified by column chromatography over silica gel (0.030–0.063 mm) with ethyl acetate:methanol (9:1, then 3:1) as eluant.
Aufarbeitung
- customThe product was purified by column chromatography over silica gel (0.030–0.063 mm) with ethyl acetate:methanol (9:1
Quellen und Nachweise
- ORD-Eintrag
- ord-c99e05e50f0f4a1e89796448ce524d33
- Quelldatensatz
- uspto-grants-2007_04
- Patentnummer
- US07208494B2
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