2,2-Dimethoxyethylmethylamine → N-[3,5-dichloro-4-(3,5-dichlorophenoxy)phenyl]-N'-(2,2-dimethoxyethyl)-N'-methylurea

HRID 1277826Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1277826
[Cl:1][C:2]1[CH:3]=[C:4]([NH:18][C:19](=[O:23])OCC)[CH:5]=[C:6]([Cl:17])[C:7]=1[O:8][C:9]1[CH:14]=[C:13]([Cl:15])[CH:12]=[C:11]([Cl:16])[CH:10]=1.[CH3:24][O:25][CH:26]([O:30][CH3:31])[CH2:27][NH:28][CH3:29]>C1(C)C=CC=CC=1>[Cl:17][C:6]1[CH:5]=[C:4]([NH:18][C:19]([N:28]([CH2:27][CH:26]([O:30][CH3:31])[O:25][CH3:24])[CH3:29])=[O:23])[CH:3]=[C:2]([Cl:1])[C:7]=1[O:8][C:9]1[CH:10]=[C:11]([Cl:16])[CH:12]=[C:13]([Cl:15])[CH:14]=1

Komponenten

4

Edukt 2

HCID 85032,2-DimethoxyethylmethylamineHCID 54304496Ethyl [3,5-dichloro-4-(3,5-dichlorophenoxy)phenyl]carbamate

Produkt 1

HCID 23451761N-[3,5-dichloro-4-(3,5-dichlorophenoxy)phenyl]-N'-(2,2-dimethoxyethyl)-N'-methylurea

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 1140TolueneLösungsmittel

Versuchsvorschrift

Ethyl [3,5-dichloro-4-(3,5-dichlorophenoxy)phenyl]carbamate (0.1 mole) and toluene (100 ml) are charged into a glass reaction vessel fitted with a mechanical stirrer, thermometer and condenser. N-(2,2-dimethoxyethyl)methanamine (0.15 mole) is added to the vessel and the mixture is refluxed for 16 hours. Solvent is then removed by mild warming under reduced pressure to yield the desired product N-[3,5-dichloro-4-(3,5-dichlorophenoxy)phenyl]-N'-(2,2-dimethoxyethyl)-N'-methylurea.

Aufarbeitung

  1. customfitted with a mechanical stirrer
  2. temperaturethe mixture is refluxed for 16 hours
  3. customSolvent is then removed
  4. temperatureby mild warming under reduced pressure

Quellen und Nachweise

ORD-Eintrag
ord-73a19c43d7cc4aa480ca98692a533ea6
Quelldatensatz
uspto-grants-1981_07
Patentnummer
US04279637

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