Phenylmethanesulfonyl chloride → HCID 86604355, Verbindung
Reaktionsgleichung
[CH2:1]([N:5]([S:15]([C:18]1[CH:23]=[CH:22][C:21]([N+:24]([O-:26])=[O:25])=[CH:20][CH:19]=1)(=[O:17])=[O:16])[C@H:6]([C:12]([OH:14])=[O:13])[CH2:7][CH2:8][CH2:9][CH2:10][NH2:11])[CH:2]([CH3:4])[CH3:3].[CH2:27]([S:34](Cl)(=[O:36])=[O:35])[C:28]1[CH:33]=[CH:32][CH:31]=[CH:30][CH:29]=1>>[CH2:1]([N:5]([S:15]([C:18]1[CH:23]=[CH:22][C:21]([N+:24]([O-:26])=[O:25])=[CH:20][CH:19]=1)(=[O:17])=[O:16])[C@H:6]([C:12]([OH:14])=[O:13])[CH2:7][CH2:8][CH2:9][CH2:10][NH:11][S:34]([CH2:27][C:28]1[CH:33]=[CH:32][CH:31]=[CH:30][CH:29]=1)(=[O:36])=[O:35])[CH:2]([CH3:4])[CH3:3]Komponenten
3
Versuchsvorschrift
Nα-isobutyl-Nα-(4-nitrobenzenesulfonyl)-L-lysine was reacted with benzylsulfonyl chloride under the conditions described in example 2 to yield 24% of the desired product.
Quellen und Nachweise
- ORD-Eintrag
- ord-34f07901f3e94095b8e2b72e44440b1b
- Quelldatensatz
- uspto-grants-2002_09
- Patentnummer