Methyl Isocyanate → HCID 152749587, Verbindung
Reaktionsgleichung
[CH3:1][N:2]=[C:3]=[O:4].[CH2:5]([O:7][C:8]([NH:10][C:11]([NH2:13])=[NH:12])=[O:9])[CH3:6]>O1CCOCC1>[CH3:1][NH:2][C:3]([NH:13][C:11]([NH:10][C:8]([O:7][CH2:5][CH3:6])=[O:9])=[NH:12])=[O:4]Komponenten
4
Edukt 2
Produkt 1
Reagenzien, Katalysatoren, Lösungsmittel 1
Versuchsvorschrift
5.1 parts by weight of methylisocyanate were added to a suspension of 10 parts by weight of ethoxycarbonylguanidine (manufactured according to Isr. J. Chem. 8, 651 [1970] ) in 60 parts by volume of anhydrous dioxane, in the course of which the temperature rose to 45°C and the precipitate dissolved. After a short time, a crystalline precipitate separated out again, which was filtered off after cooling and washed with ether. It was dried in vacuo over P2O5 and paraffin chips.
Aufarbeitung
- customrose to 45°C
- dissolutionthe precipitate dissolved
- customAfter a short time, a crystalline precipitate separated out again
- filtrationwhich was filtered off
- temperatureafter cooling
- washwashed with ether
- dry with materialIt was dried in vacuo over P2O5 and paraffin chips
Quellen und Nachweise
- ORD-Eintrag
- ord-51945f79540847859e7fa2d8d68636ae
- Quelldatensatz
- uspto-grants-1976_08
- Patentnummer
- US03972870
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