Potassium Hydroxide → N,N'-bis(4-anilinophenyl)-2,12-dimethyl-4,7,10-trithiatridecanediamide

HRID 1283480

Reaktionsgleichung

Reaktionsgleichung von HRID 1283480
[SH:1][CH2:2][CH2:3][S:4][CH2:5][CH2:6][SH:7].[NH:8]([C:15]1[CH:20]=[CH:19][C:18]([NH:21][C:22](=[O:26])[C:23]([CH3:25])=[CH2:24])=[CH:17][CH:16]=1)[C:9]1[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=1.[OH-:27].[K+]>C(O)C>[NH:8]([C:15]1[CH:16]=[CH:17][C:18]([NH:21][C:22](=[O:26])[CH:23]([CH3:25])[CH2:24][S:1][CH2:2][CH2:3][S:4][CH2:5][CH2:6][S:7][CH2:24][CH:23]([CH3:25])[C:22]([NH:21][C:18]2[CH:19]=[CH:20][C:15]([NH:8][C:9]3[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=3)=[CH:16][CH:17]=2)=[O:27])=[CH:19][CH:20]=1)[C:9]1[CH:10]=[CH:11][CH:12]=[CH:13][CH:14]=1

Komponenten

5

Edukt 3

HCID 14797Potassium HydroxideHCID 77117Bis(2-mercaptoethyl) sulfideHCID 1624682-Propenamide, 2-methyl-N-(4-(phenylamino)phenyl)-

Produkt 1

HCID 21518137N,N'-bis(4-anilinophenyl)-2,12-dimethyl-4,7,10-trithiatridecanediamide

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 702EthanolLösungsmittel2×

Reaktionsbedingungen

Temperatur
50 °C

Versuchsvorschrift

Sixty-one grams of 2-mercaptoethyl sulfide was added to a solution of 200 grams of N-(4-anilinophenyl) methacrylamide in 2450 milliliters of ethanol. A solution of 5 grams of potassium hydroxide in 50 milliliters of ethanol was then added, and the mixture was heated at 50°C. for 5 hours. Product began to precipitate after about 2 hours. The mixture was then allowed to cool to room temperature and the solid product was filtered off. The product, after drying, weighed 231.5 grams (89 percent of theory) and melted at 131° to 133.5°C.

Aufarbeitung

  1. customto precipitate after about 2 hours
  2. temperatureto cool to room temperature
  3. filtrationthe solid product was filtered off
  4. customThe product, after drying

Quellen und Nachweise

ORD-Eintrag
ord-2359960700c54f4585be3a0945ea3e63
Quelldatensatz
uspto-grants-1976_08
Patentnummer
US03975414

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