Benzyl Bromide → 12-Benzyloxy-octadecanoic acid

Reaktionsgleichung

[OH:1][CH:2]([CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH3:22])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][C:13]([O:15]C)=[O:14].[CH2:23](Br)[C:24]1[CH:29]=[CH:28][CH:27]=[CH:26][CH:25]=1>>[CH2:23]([O:1][CH:2]([CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH3:22])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][C:13]([OH:15])=[O:14])[C:24]1[CH:29]=[CH:28][CH:27]=[CH:26][CH:25]=1

Komponenten

Edukt 2

HCID 7498Benzyl Bromide

HCID 8840Methyl 12-hydroxystearate

Produkt 1

HCID 1892047212-Benzyloxy-octadecanoic acid

Versuchsvorschrift

In a similar manner to Example 4-(1), methyl 12-hydroxyoctadecanoate was used instead of ethyl ricinoleate and benzyl bromide was used instead of methyl iodide, the title compound (8-i) was obtained.

Quellen und Nachweise

ORD-Eintrag: ord-ac7eed5ae39f4fc99c8d690e393a226a
Quelldatensatz: uspto-grants-1998_05
DOI: 10.6084/m9.figshare.5104873.v1
Patentnummer: US05753707

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