Hydrogen Peroxide → Bis[1-(2-methyl-2-phenylpropyloxy)-2,2,6,6-tetramethylpiperidin-4-yl] adipate

HRID 133634

Reaktionsgleichung

Reaktionsgleichung von HRID 133634
[C:1]([O:21][CH:22]1[CH2:27][C:26]([CH3:29])([CH3:28])[N:25]([OH:30])[C:24]([CH3:32])([CH3:31])[CH2:23]1)(=[O:20])[CH2:2][CH2:3][CH2:4][CH2:5][C:6]([O:8][CH:9]1[CH2:14][C:13]([CH3:16])([CH3:15])[N:12]([OH:17])[C:11]([CH3:19])([CH3:18])[CH2:10]1)=[O:7].OO.[C:35]([C:39]1[CH:44]=[CH:43][CH:42]=[CH:41][CH:40]=1)([CH3:38])([CH3:37])[CH3:36]>C(#N)C>[C:1]([O:21][CH:22]1[CH2:23][C:24]([CH3:32])([CH3:31])[N:25]([O:30][CH2:36][C:35]([CH3:38])([C:39]2[CH:44]=[CH:43][CH:42]=[CH:41][CH:40]=2)[CH3:37])[C:26]([CH3:29])([CH3:28])[CH2:27]1)(=[O:20])[CH2:2][CH2:3][CH2:4][CH2:5][C:6]([O:8][CH:9]1[CH2:14][C:13]([CH3:16])([CH3:15])[N:12]([O:17][CH2:36][C:35]([CH3:38])([C:39]2[CH:44]=[CH:43][CH:42]=[CH:41][CH:40]=2)[CH3:37])[C:11]([CH3:19])([CH3:18])[CH2:10]1)=[O:7]

Komponenten

5

Edukt 3

HCID 784Hydrogen PeroxideHCID 7366Tert-ButylbenzeneHCID 57039687Bis(1-oxyl-2,2,6,6-tetramethyl-pieridin-4-yl)adipate

Produkt 1

HCID 50943318Bis[1-(2-methyl-2-phenylpropyloxy)-2,2,6,6-tetramethylpiperidin-4-yl] adipate

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 6342AcetonitrileLösungsmittel

Versuchsvorschrift

The title compound is prepared from the reaction of bis(1-oxyl-2,2,6,6-tetramethylpiperidin-4-yl) adipate, aqueous hydrogen peroxide, ferric chloride hexahydrate; acetonitrile, and tert-butylbenzene following a procedure similar to that of Example 6.

Quellen und Nachweise

ORD-Eintrag
ord-64b61b75dc6a411aa60355191c3a0acd
Quelldatensatz
uspto-grants-2008_06
Patentnummer
US07390904B2

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