Reaktionsgleichung
[O:1]([CH2:8][CH2:9][OH:10])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[OH-].[K+].C1OC1C.C1OC1.C1OC1C.C1OC1.S(=O)(=O)(O)O>>[O:1]([CH2:8][CH2:9][OH:10])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[CH3:3][CH2:2][O:1][CH2:8][CH3:9]Komponenten
Reaktionsbedingungen
- Temperatur
- 110 °C
Versuchsvorschrift
To a clean, dry stirred tank pressure vessel with nitrogen inlet is charged 1553.93 g (11.25 moles) of 2-Phenoxyethanol and a catalytic amount (16.67 g) of 45% KOH. The vessel is purged with nitrogen and heated to 110° C. Vacuum is applied for 1 hour to remove trace amounts of water and the temperature is raised to 150° C. A mixture of 1919.03 g (33.04 moles) of Propylene Oxide and 873.28 g (19.82 moles) of Ethylene Oxide is added at a constant rate to keep the pressure below 50 psig. After all Propylene Oxide/Ethylene Oxide is added, the reaction mixture is allowed to react for an additional hour after which the temperature is lowered to 110° C. and vacuum is applied for one hour. The reaction mixture is cooled to 65° C. and the catalyst is neutralized with an equivalent molar amount of 25% Sulfuric Acid.
Aufarbeitung
- customTo a clean, dry
- customThe vessel is purged with nitrogen
- customto remove trace amounts of water
- temperaturethe temperature is raised to 150° C
- additionis added at a constant rate
- customto react for an additional hour after which the temperature
- customis lowered to 110° C.
- waitvacuum is applied for one hour
- temperatureThe reaction mixture is cooled to 65° C.
Quellen und Nachweise
- ORD-Eintrag
- ord-cd2a26beed3248838ac77f6eb2ea193b
- Quelldatensatz
- uspto-grants-2007_05
- Patentnummer
- US07217424B2
Verknüpfte Notizen
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