HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
Thiophosgene → 3-Phenoxyphenylisothiocyanate
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | Thiophosgene | HCID 10040 | — |
| Edukt | 3-Phenoxyaniline | HCID 77135 | — |
| Edukt | Ethyl acetate hexane | HCID 21226206 | — |
| Lösungsmittel | Acetone | HCID 180 | — |
| Produkt | 3-Phenoxyphenylisothiocyanate | HCID 22041281 | — |
Reaktionsschritte
To a stirring solution of 3-phenoxyaniline (185 mg, 1.0 mmol) in acetone (4.0 mL) at 0° C. was added thiophosgene (0.23 mL, 3.0 mmol) and the resulting reaction maintained for 30 min. The reaction determined complete by TLC (4:1 hexane/EtOAc). The reaction was concentrated, azeotroped with toluene and taken on without further purification.
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US07728010B2 |
| Quelldatensatz | uspto-grants-2010_06 |
| ORD ID | ord-b272333b6f17485f927833b273755ad7 |
| Quellennotiz | uspto-grants-2010_06 |