Bis(trimethylstannyl)indene → HCID 178477784, Verbindung

HRID 1354511Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1354511
[Cl-:1].[Cl-].[Cl-].[CH:4]1([Zr+3:9])[CH:8]=[CH:7][CH:6]=[CH:5]1.[CH3:10][Sn:11]([C:14]1[CH:15]([Sn](C)(C)C)[C:16]2[C:21]([CH:22]=1)=[CH:20][CH:19]=[CH:18][CH:17]=2)([CH3:13])[CH3:12]>C1(C)C=CC=CC=1>[Cl-:1].[Cl-:1].[CH3:10][Sn:11]([C:14]1[CH:15]([Zr+2:9][CH:4]2[CH:8]=[CH:7][CH:6]=[CH:5]2)[C:16]2[C:21]([CH:22]=1)=[CH:20][CH:19]=[CH:18][CH:17]=2)([CH3:13])[CH3:12]

Komponenten

4

Edukt 2

HCID 69432104Bis(trimethylstannyl)indeneHCID 178478629HCID 178478629, Verbindung

Produkt 1

HCID 178477784HCID 178477784, VerbindungAusbeute 177,1 %

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 1140TolueneLösungsmittel2×

Versuchsvorschrift

Cyclopentadienylzirconium trichloride (CpZrCl3, 3.94 g, 15.0 mmol) which was slurrified by adding toluene of 70 ml was added into the mixed solution including bis(trimethylstannyl)indene (6.75 g, 15.28 mmol) and toluene of 100 ml, and then reacted for 21 hours at 85° C. Yellowish (trimethylstannyl-indenyl)(cyclopentadienyl)zirconium dichloride compound (6.71 g, yield: 86%) was obtained by a series of processes, such as removing toluene from reactant, slurrifying the obtained solid by adding hexane (100 ml) and filtering the slurry.

Aufarbeitung

  1. additionwas added into the mixed solution
  2. customreacted for 21 hours at 85° C

Quellen und Nachweise

ORD-Eintrag
ord-3a68c936c1b949759705c002a0c1a4d3
Quelldatensatz
uspto-grants-2007_05
Patentnummer
US07223824B2

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