(4-Pyridylthio)acetic acid → 2-(4'-Methoxy-biphenyl-4-ylsulfanyl)-acetic acid
Reaktionsgleichung
CC1C=C(SC[C:11](O)=[O:12])C=C(C)C=1.N1C=CC(SCC(O)=O)=CC=1.[C:25]1([C:36]2[CH:41]=[CH:40][CH:39]=[CH:38][CH:37]=2)[CH:30]=[CH:29][C:28]([S:31][CH2:32][C:33]([OH:35])=[O:34])=[CH:27][CH:26]=1>>[CH3:11][O:12][C:39]1[CH:38]=[CH:37][C:36]([C:25]2[CH:30]=[CH:29][C:28]([S:31][CH2:32][C:33]([OH:35])=[O:34])=[CH:27][CH:26]=2)=[CH:41][CH:40]=1Komponenten
4
Versuchsvorschrift
was acylated with (3,5-dimethyl-phenylsulfanyl)acetic acid, with pyridin-4-ylsulfanyl-acetic acid, with 2-(biphenyl-4-ylsulfanyl)-acetic acid, and with 2-(4′-methoxy-biphenyl-4-ylsulfanyl)-acetic acid, respectively, to give the following compounds as pale-yellow solids: