Acetone → 6-Methyl-2-heptanone

HRID 1370775

Reaktionsgleichung

Reaktionsgleichung von HRID 1370775
[CH:1](=O)[CH2:2][CH:3]([CH3:5])[CH3:4].[CH3:7][C:8]([CH3:10])=[O:9]>>[CH3:4][CH:3]([CH3:5])[CH2:2][CH2:1][CH2:7][C:8](=[O:9])[CH3:10]

Komponenten

3

Versuchsvorschrift

To aid comprehension, the reaction will be explained here by the example of the reaction of acetone with isovaleraldehyde to produce 6-methylheptan-2-one. The reaction takes place “in situ” via the stage of aldol condensation with the formation of the corresponding β-hydroxyketone, which is not isolated. Dehydration to 6-methylhept-3-en-2-one takes place under the reaction conditions, and this is hydrogenated selectively to the corresponding methylketone with the hydrogenation catalyst distributed homogeneously in the aqueous catalyst phase.

Aufarbeitung

  1. customthe reaction

Quellen und Nachweise

ORD-Eintrag
ord-f282adfabe8d45cda6642831763bf31f
Quelldatensatz
uspto-grants-2003_06
Patentnummer
US06583323B2

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