HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
Isopropenyl acetate → (+)-Styrallyl acetate
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | Isopropenyl acetate | HCID 7916 | — |
| Edukt | 4-Chlorophenyl Acetate | HCID 13410 | — |
| Produkt | (+)-Styrallyl acetate | HCID 6951704 | 95% |
Reaktionsschritte
The procedure of Example 1 was repeated except that 3 molar equivalents of p-chlorophenyl acetate (a conventional acylating agent) was used in place of isopropenyl acetate in the presence of three times the amount of the enzyme catalyst used in Example 1 over a reaction period of 42 hours, to obtain (R)-1-phenylethyl acetate having an optical purity of higher than 99%, at a yield of 95%.
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US07156731B2 |
| Quelldatensatz | uspto-grants-2007_01 |
| ORD ID | ord-1bc0273f6d9e4898b5a2d888224182f6 |
| Quellennotiz | uspto-grants-2007_01 |