1-Bromohexane → HCID 11732181, Verbindung

HRID 1383705Notizen

Reaktionsgleichung

[Cl:1][C:2]1[CH:14]=[CH:13][C:12]2[C:11]3[C:6](=[CH:7][C:8]([Cl:15])=[CH:9][CH:10]=3)[CH2:5][C:4]=2[CH:3]=1.Br[CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH3:22]>>[Cl:1][C:2]1[CH:14]=[CH:13][C:12]2[C:11]3[C:6](=[CH:7][C:8]([Cl:15])=[CH:9][CH:10]=3)[C:5]([CH2:13][CH2:14][CH2:2][CH2:3][CH2:4][CH3:12])([CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH3:22])[C:4]=2[CH:3]=1

Komponenten

Edukt 2

HCID 81011-Bromohexane

HCID 2519872,7-Dichlorofluorene

Produkt 1

HCID 11732181HCID 11732181, VerbindungAusbeute 91 %

Versuchsvorschrift

2,7-Dichloro-9,9-di(1-hexyl)fluorene was prepared from 2,7-dichlorofluorene and 1-bromohexane following the procedure of Example 1 as colorless crystals (recrystallized from hexane) in 91 percent yield; melting point 66° C. to 67° C. HPLC analysis showed that the sample was 99 percent or greater pure and the spectral data confirmed the title structure.

Aufarbeitung

customas colorless crystals (recrystallized from hexane) in 91 percent yield

Quellen und Nachweise

ORD-Eintrag: ord-792813a0ffbe49b8af04afd122974de5
Quelldatensatz: uspto-grants-2001_07
DOI: 10.6084/m9.figshare.5104873.v1
Patentnummer: US06255447B1

Notizen zur Reaktion

Wird geladen…