Pyridine → HCID 13281344, Verbindung
Reaktionsgleichung
Cl[C:2]1[C:7]2[CH2:8][CH2:9][CH2:10][CH2:11][C:12]3[CH:17]=[CH:16][CH:15]=[CH:14][C:13]=3[C:6]=2[CH:5]=[CH:4][CH:3]=1.[N:18]1C=CC=C[CH:19]=1>>[CH:5]1[C:6]2[C:13]3[CH:14]=[CH:15][CH:16]=[CH:17][C:12]=3[CH2:11][CH2:10][CH2:9][CH2:8][C:7]=2[C:2]([C:19]#[N:18])=[CH:3][CH:4]=1Komponenten
3
Versuchsvorschrift
The reaction of 4-chloro-5,6,7,8-tetrahydrodibenzo[a,c]-cyclooctene (3.3 g, 0.014 mole), cuprous cyanide (2.44 g, 0.027 mole) and pyridine (2.5 g, 0.027 mole) produced 5,6,7,8-tetrahydrodibenzo[a,c]cycloocten-4-carbonitrile as an oil (60% product, 40% starting material by gas chromatography). The IR spectrum possesses an adsorption at 4.45μ indicating a CN group.
Quellen und Nachweise
- ORD-Eintrag
- ord-ebfe49c6f7624c59b38718243be24d95
- Quelldatensatz
- uspto-grants-1984_02
- Patentnummer
- US04433182
Notizen zur Reaktion
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