HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
Dimethylformamide → 4-Benzyloxy-2-(trifluoromethyl)benzaldehyde
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | Dimethylformamide | HCID 6228 | — |
| Edukt | 4-(Benzyloxy)-1-bromo-2-(trifluoromethyl)benzene | HCID 22273864 | — |
| Edukt | Butyllithium | HCID 178418339 | — |
| Lösungsmittel | Tetrahydrofuran | HCID 8028 | — |
| Produkt | 4-Benzyloxy-2-(trifluoromethyl)benzaldehyde | HCID 22273885 | — |
Reaktionsschritte
In analogy to the procedure described in example 8 c], 1-bromo-2-trifluoromethyl-4-(phenylmethoxy)-benzene was treated with n-BuLi and N,N-dimethylformamide in dry tetrahydrofuran to yield 4-benzyloxy-2-trifluoromethyl-benzaldehyde as colorless liquid.
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US07348349B2 |
| Quelldatensatz | uspto-grants-2008_03 |
| ORD ID | ord-4fec9ded67af43b6adb7ed2ffd35d9cd |
| Quellennotiz | uspto-grants-2008_03 |